Reactivity of supported nickel catalysts prepared by gas phase methods.
نویسندگان
چکیده
منابع مشابه
Structural and Catalytic Properties of Model Supported Nickel Catalysts
published in Aduonce ACS Abstracts, January 1, 1994. 0022-36S4/94/2098-124S%04.S0/0 nation at present. Martini2 and Goodmani3 have suggested that the activity of different crystal planes toward hydrogenolysis is responsible for the observed variations in activity with metal particle size. Single-crystal surface science studies have shown these structure-sensitive reactions to proceed more rapid...
متن کاملPolymer-Supported Raney Nickel Catalysts for Sustainable Reduction Reactions.
Green is the future of chemistry. Catalysts with high selectivity are the key to green chemistry. Polymer-supported Raney catalysts have been found to have outstanding performance in the clean preparation of some chemicals. For example, a polyamide 6-supported Raney nickel catalyst provided a 100.0% conversion of n-butyraldehyde without producing any detectable n-butyl ether, the main byproduct...
متن کاملGas-Phase Hydroformylation of Propene over Silica-Supported PPh3-Modified Rhodium Catalysts
Heterogeneous rhodium catalysts supported on SiO2 were modified with PPh3 for the gas-phase hydroformylation of propene to produce nand isobutanal. High selectivity to aldehydes was achieved, with no propane or alcohols formed. Investigation of the effects of reaction temperature, reactant partial pressures, total pressure, and PPh3/Rh ratio suggested that the supported catalyst behaved similar...
متن کاملOxidation of methanol to formaldehyde on supported vanadium oxide catalysts compared to gas phase molecules.
The oxidation of methanol to formaldehyde on silica supported vanadium oxide is studied by density functional theory. For isolated vanadium oxide species silsesquioxane-type models are adopted. The first step is dissociative adsorption of methanol yielding CH3O(O=)V(O-)2 surface complexes. This makes the O=V(OCH3)3 molecule a suited model system. The rate-limiting oxidation step involves hydrog...
متن کاملSupported Rh-phosphine complex catalysts for continuous gas-phase decarbonylation of aldehydes.
Heterogeneous silica supported rhodium-phosphine complex catalysts are employed for the first time in the catalytic decarbonylation of aldehydes in continuous gas-phase. The reaction protocol is exemplified for the decarbonylation of p-tolualdehyde to toluene and further extended to other aromatic and aliphatic aldehydes achieving excellent results in terms of both conversion and selectivity.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of The Japan Petroleum Institute
سال: 1989
ISSN: 0582-4664
DOI: 10.1627/jpi1958.32.15